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List of S Phrases
Inhalt:
Hints:
- Links of S phrases point to the Council Directive 67/548/EEC. You will find there notes on how to use the S-phrase.
- In this list you will also find some modifications of S phrases made by manufacturers. These modifications are preceded by the company name.
S Phrases:
| S1: | Keep locked up. |
| S2: | Keep out of the reach of children. |
| S3: | Keep in a cool place. |
| S4: | Keep away from living quarters. |
| S5: | Keep contents under ... (appropriate liquid to be specified by the manufacturer). |
| Merck S5.1: | Keep contents under water. |
| Merck S5.2: | Keep contents under petroleum. |
| Merck S5.3: | Keep contents under paraffin oil. |
| Riedel-de Haen S5A: | Keep contents under paraffin oil. |
| Riedel-de Haen S5B: | Keep contents under petroleum. |
| Riedel-de Haen S5C: | Keep contents under protecting liquid. |
| S6: | Keep contents under ... (appropriate gas to be specified by the manufacturer). |
| Merck S6.1: | Keep contents under nitrogen. |
| Merck S6.2: | Keep contents under argon. |
| Merck S6.3: | Keep contnts under carbon dioxide. |
| Riedel-de Haen S6A: | Keep contents under protecting gas. |
| Riedel-de Haen S6B: | Keep contents under nitrogen. |
| Riedel-de Haen S6C: | Keep contents under argon. |
| S7: | Keep container tightly closed. |
| S8: | Keep container dry. |
| S9: | Keep container in a well-ventilated place. |
| S10 (obsolete): | Keep content wet. (This S phrase is no longer designated by the version of the GefStoffV published on 26.10.93.) |
| S11(obsolete): | Avoid contact with
air. (This S phrase is no longer designated by the version of the GefStoffV published on 26.10.93.) |
| S12: | Do not keep the container sealed. |
| S13: | Keep away from food, drink and animal feedingstuffs. |
| S14: | Keep away from ... (incompatible materials to be indicated by the manufacturer) |
| Merck S14.1: | Keep away from reducing agents, heavy metal compounds, acids and alkalies. |
| Merck S14.2: | Keep away from oxidizing and acidic agents and heavy metal compounds. |
| Merck S14.3: | Keep away from iron. |
| Merck S14.4: | Keep away from water and lyes. |
| Merck S14.5: | Keep away from acids. |
| Merck S14.6: | Keep away from lyes. |
| Merck S14.7: | Keep away from metals. |
| Merck S14.8: | Keep away from oxidizing and acidic agents. |
| Merck S14.9: | Keep away from combustible organic compounds. |
| Merck S14.10: | Keep away from acids, reducing agents and combustible materials. |
| Merck S14.11: | Keep away from combustible
material. (This is unnecessary because it equals S17!) |
| S15: | Keep away from heat. |
| S16: | Keep away from sources of ignition - No smoking. |
| S17: | Keep away from combustible material. |
| S18: | Handle and open container with care. |
| S20: | When using do not eat or drink. |
| S21: | When using do not smoke. |
| S22: | Do not breathe dust. |
| S23: | Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer). |
| Merck S23.1: | Do not breath gas. |
| Merck S23.2: | Do not breath vapour. |
| Merck S23.3: | Do not breath spray. |
| Merck S23.4: | Do not breath fumes. |
| Merck S23.5: | Do not breathe vapor/spray. |
| Riedel-de Haen S23A: | Do not breath gas. |
| Riedel-de Haen S23B: | Do not breath fumes. |
| Riedel-de Haen S23C: | Do not breath spray. |
| S24: | Avoid contact with skin. |
| S25: | Avoid contact with eyes. |
| S26: | In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. |
| S27: | Take off immediately all contaminated clothing. |
| S28: | After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer). |
| Merck S28.1: | After contact with skin, wash immediately with plenty of water. |
| Merck S28.2: | After contact with skin, wash immediately with plenty of water and soap. |
| Merck S28.3: | After contact with skin, wash immediately with plenty of water and soap, if possible also with polyethylene glycol 400. |
| Merck S28.4: | After contact with skin, wash immediately with plenty of polyethylene glycol 300 and ethanol (2:1) and afterwards with plenty of water and soap. |
| Merck S28.5: | After contact with skin, wash immediately with plenty of polyethylene glycol 400. |
| Merck S28.6: | After contact with skin, wash immediately with plenty of polyethylene glycol 400 and afterwards clean with plenty of water. |
| Merck S28.7: | After contact with skin, wash immediately with plenty of water and acidic soap. |
| Riedel-de Haen S28A: | After contact with skin, wash immediately with plenty of a 2% copper(II)-sulfate solution . |
| Riedel-de Haen S28B: | After contact with skin, wash immediately with plenty of polyethylene glycol. |
| Riedel-de Haen S28C: | After contact with skin, wash immediately with plenty of polyethylene glycol / ethanol (1:1). |
| Riedel-de Haen S28D: | After contact with skin, wash immediately with plenty of water and soap. |
| S29: | Do not empty into drains. |
| S30: | Never add water to this product. |
| S31 (obsolete): | Keep away from explosive
materials. (This S-phrase is no longer designated by the version of the GefStoffV published on 26.10.93.) |
| S33: | Take precautionary measures against static discharges. |
| S34 (obsolete): | Avoid strokes and
frictions. (This S-phrase is no longer designated by the version of the GefStoffV published on 26.10.93.) |
| S35: | This material and its container must be disposed of in a safe way. |
| Merck S35.1: | This material and its container must be disposed of by treating with a 2% sodium hydroxide solution. |
| S36: | Wear suitable protective clothing. |
| S37: | Wear suitable gloves. |
| S38: | In case of insufficient ventilation, wear suitable respiratory equipment. |
| S39: | Wear eye/face protection. |
| S40: | To clean the floor and all objects contaminated by this material, use ... (to be specified by the manufacturer). |
| Merck S40.1: | To clean the floor and contaminated objects, use water. |
| Riedel-de Haen S40A: | To clean the floor and contaminated objects, use iodized active carbon. |
| S41: | In case of fire and/or explosion do not breathe fumes. |
| S42: | During fumigation/spraying wear suitable respiratory equipment (appropriate wording to be specified by the manufacturer) |
| S43: | In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases risk, add - 'Never use water') |
| Merck S43.1: | In case of fire use water. |
| Merck S43.2: | In case of fire use water or powder. |
| Merck S43.3: | In case of fire use fire powder. Never use water. |
| Merck S43.4: | In case of fire use carbon dioxide. Never use water. |
| Merck S43.6: | In case of fire use sand. Never use water. |
| Merck S43.7: | In case of fire use metal fire powder. Never use water. |
| Merck S43.8: | In case of fire use sand, carbon dioxide or fire powder. Never use water. |
| Riedel-de Haen S43A: | In case of fire use sand. Never use water. |
| S44 (obsolete): | If you feel unwell, seek medical advice
immediately. (Show the label where possible.) (This S-phrase is no longer designated by the version of the GefStoffV published on 26.10.93.) |
| S45: | In case of accident or if you feel unwell, seek medical advice immediately. (Show the label where possible.) |
| S46: | If swallowed, seek medical advice immediately and show this container or label. |
| S47: | Keep at temperature not exceeding ... °C. (To be specified by the manufacturer.) |
| FU-Safety data base S4730: | Keep at temperature not exceeding 30 °C. |
| FU-Safety data base S4740: | Keep at temperature not exceeding 40 °C. |
| S48: | Keep wet with ... (appropriate material to be specified by the manufacturer) |
| Merck S48.1: | Keep wet with water. |
| Riedel-de Haen S48A: | Keep wet with water. |
| S49: | Keep only in the original container |
| S50: | Do not mix with ... (to be specified by the manufacturer) |
| Merck S50.1: | Do not mix with acids. |
| Merck S50.2: | Do not mix with lyes. |
| Merck S50.3: | Do not mix with strong acids or lyes, nonferrous heavy metals and their salts. |
| S51: | Use only in well-ventilated areas. |
| S52: | Not recommended for interior use on large surface areas. |
| S53: | Avoid exposure - obtain special instructions before use. |
| S54 (obsolete): | Before draining of to sewage disposal plant ask for
permission of the competent authority. (This S-phrase is no longer designated by the version of the GefStoffV published on 26.10.93.) |
| S55 (obsolete): | Before draining of into the sewage system or into
waters treat according to state of art. (This S-phrase is no longer designated by the version of the GefStoffV published on 26.10.93.) |
| S56: | Dispose of this material and its container at hazardous or special waste collection point. |
| S57: | Use appropriate container to avoid environmental contamination. |
| S58 (obsolete): | Dispose as hazardous waste. (This S-phrase is no longer designated by the version of the GefStoffV published on 26.10.93.) |
| S59: | Refer to manufacturer/supplier for information on recovery/recycling |
| S60: | This material and its container must be disposed of as hazardous waste. |
| S61: | Avoid release to the environment. Refer to special instructions / Safety data sheets. |
| S62: | If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. |
| S63: | In case of accident by inhalation: remove casualty to fresh air and keep at rest. |
| S64: | If swallowed, rinse mouth with water (only if the person is conscious). |
Combinations of S Phrases:
| S1/2: | Keep locked up and out of the reach of children. |
| S3/7: | Keep container tightly closed in a cool place. |
| S3/7/9 (obsolete): | Keep container tightly closed in a cool, well-ventilated place. |
| S3/9 (obsolete): | Keep container in a cool, well-ventilated place. |
| S3/9/14: | Keep in a cool, well-ventilated place away from ... (incompatible materials to be indicated by the manufacturer) |
| S3/9/14/49: | Keep only in the original container in a cool, well-ventilated place away from ... (incompatible materials to be indicated by the manufacturer) |
| S3/9/49: | Keep only in the original container in a cool well-ventilated place. |
| S3/14: | Keep in a cool place away from ... (incompatible materials to be indicated by the manufacturer) |
| S7/8: | Keep container tightly closed and dry. |
| S7/9: | Keep container tightly closed and in a well-ventilated place. |
| S7/47: | Keep container tightly closed and at a temperature not exceeding ... °C (to be specified by the manufacturer). |
| S20/21: | When using do not eat, drink or smoke. |
| S24/25: | Avoid contact with skin and eyes. |
| S27/28: | Take off immediately all contaminated clothing. After contact with skin, wash immediately with plenty of ......(to be specified by the manufacturer) |
| S29/35: | Do not empty into drains. This material and its container must be disposed of in a safe way. |
| S29/56: | Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point. |
| S36/37: | Wear suitable protective clothing and gloves. |
| S36/37/39: | Wear suitable protective clothing, gloves and eye/face protection. |
| S36/39: | Wear suitable protective clothing and eye/face protection. |
| S37/39: | Wear suitable gloves and eye/face protection. |
| S47/49: | Keep only in the original container at a temperature not exceeding ... °C (to be specified by the manufacturer) |
Burkhard Kirste, 1994-07-08, Thomas Lehmann, 1996-01-02; last modification: 2009-01-21
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2 May 2013:
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