S Phrases


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List of S Phrases

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S Phrases:

S1: Keep locked up.
S2: Keep out of the reach of children.
S3: Keep in a cool place.
S4: Keep away from living quarters.
S5: Keep contents under ... (appropriate liquid to be specified by the manufacturer).
Merck S5.1: Keep contents under water.
Merck S5.2: Keep contents under petroleum.
Merck S5.3: Keep contents under paraffin oil.
Riedel-de Haen S5A: Keep contents under paraffin oil.
Riedel-de Haen S5B: Keep contents under petroleum.
Riedel-de Haen S5C: Keep contents under protecting liquid.
S6: Keep contents under ... (appropriate gas to be specified by the manufacturer).
Merck S6.1: Keep contents under nitrogen.
Merck S6.2: Keep contents under argon.
Merck S6.3: Keep contnts under carbon dioxide.
Riedel-de Haen S6A: Keep contents under protecting gas.
Riedel-de Haen S6B: Keep contents under nitrogen.
Riedel-de Haen S6C: Keep contents under argon.
S7: Keep container tightly closed.
S8: Keep container dry.
S9: Keep container in a well-ventilated place.
S10 (obsolete): Keep content wet.
(This S phrase is no longer designated by the version of  the GefStoffV published on 26.10.93.)
S11(obsolete): Avoid contact with air.
(This S phrase is no longer designated by the version of  the GefStoffV published on 26.10.93.)
S12: Do not keep the container sealed.
S13: Keep away from food, drink and animal feedingstuffs.
S14: Keep away from ... (incompatible materials to be indicated by the manufacturer)
Merck S14.1: Keep away from reducing agents, heavy metal compounds, acids and alkalies.
Merck S14.2: Keep away from oxidizing and acidic agents and heavy metal compounds.
Merck S14.3: Keep away from iron.
Merck S14.4: Keep away from water and lyes.
Merck S14.5: Keep away from acids.
Merck S14.6: Keep away from lyes.
Merck S14.7: Keep away from metals.
Merck S14.8: Keep away from oxidizing and acidic agents.
Merck S14.9: Keep away from combustible organic compounds.
Merck S14.10: Keep away from acids, reducing agents and combustible materials.
Merck S14.11: Keep away from combustible material.
(This is unnecessary because it equals S17!)
S15: Keep away from heat.
S16: Keep away from sources of ignition - No smoking.
S17: Keep away from combustible material.
S18: Handle and open container with care.
S20: When using do not eat or drink.
S21: When using do not smoke.
S22: Do not breathe dust.
S23: Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).
Merck S23.1: Do not breath gas.
Merck S23.2: Do not breath vapour.
Merck S23.3: Do not breath spray.
Merck S23.4: Do not breath fumes.
Merck S23.5: Do not breathe vapor/spray.
Riedel-de Haen S23A: Do not breath gas.
Riedel-de Haen S23B: Do not breath fumes.
Riedel-de Haen S23C: Do not breath spray.
S24: Avoid contact with skin.
S25: Avoid contact with eyes.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S27: Take off immediately all contaminated clothing.
S28: After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer).
Merck S28.1: After contact with skin, wash immediately with plenty of water.
Merck S28.2: After contact with skin, wash immediately with plenty of water and soap.
Merck S28.3: After contact with skin, wash immediately with plenty of water and soap, if possible also with polyethylene glycol 400.
Merck S28.4: After contact with skin, wash immediately with plenty of polyethylene glycol 300 and ethanol (2:1) and afterwards with plenty of water and soap.
Merck S28.5: After contact with skin, wash immediately with plenty of polyethylene glycol 400.
Merck S28.6: After contact with skin, wash immediately with plenty of polyethylene glycol 400 and afterwards clean with plenty of water.
Merck S28.7: After contact with skin, wash immediately with plenty of water and acidic soap.
Riedel-de Haen S28A: After contact with skin, wash immediately with plenty of  a 2% copper(II)-sulfate solution .
Riedel-de Haen S28B: After contact with skin, wash immediately with plenty of polyethylene glycol.
Riedel-de Haen S28C: After contact with skin, wash immediately with plenty of polyethylene glycol / ethanol (1:1).
Riedel-de Haen S28D: After contact with skin, wash immediately with plenty of water and soap.
S29: Do not empty into drains.
S30: Never add water to this product.
S31 (obsolete): Keep away from explosive materials.
(This S-phrase is no longer designated by the version of  the GefStoffV published on 26.10.93.)
S33: Take precautionary measures against static discharges.
S34 (obsolete): Avoid strokes and frictions.
(This S-phrase is no longer designated by the version of  the GefStoffV published on 26.10.93.)
S35: This material and its container must be disposed of in a safe way.
Merck S35.1: This material and its container must be disposed of by treating with a 2% sodium hydroxide solution.
S36: Wear suitable protective clothing.
S37: Wear suitable gloves.
S38: In case of insufficient ventilation, wear suitable respiratory equipment.
S39: Wear eye/face protection.
S40: To clean the floor and all objects contaminated by this material, use ... (to be specified by the manufacturer).
Merck S40.1: To clean the floor and contaminated objects, use water.
Riedel-de Haen S40A: To clean the floor and contaminated objects, use iodized active carbon.
S41: In case of fire and/or explosion do not breathe fumes.
S42: During fumigation/spraying wear suitable respiratory equipment (appropriate wording to be specified by the manufacturer)
S43: In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases risk, add - 'Never use water')
Merck S43.1: In case of fire use water.
Merck S43.2: In case of fire use water or powder.
Merck S43.3: In case of fire use fire powder. Never use water.
Merck S43.4: In case of fire use carbon dioxide. Never use water.
Merck S43.6: In case of fire use sand. Never use water.
Merck S43.7: In case of fire use metal fire powder. Never use water.
Merck S43.8: In case of fire use sand, carbon dioxide or fire powder. Never use water.
Riedel-de Haen S43A: In case of fire use sand. Never use water.
S44 (obsolete): If you feel unwell, seek medical advice immediately. (Show the label where possible.)
(This S-phrase is no longer designated by the version of  the GefStoffV published on 26.10.93.)
S45: In case of accident or if you feel unwell, seek medical advice immediately. (Show the label where possible.)
S46: If swallowed, seek medical advice immediately and show this container or label.
S47: Keep at temperature not exceeding ... °C. (To be specified by the manufacturer.)
FU-Safety data base S4730: Keep at temperature not exceeding 30 °C.
FU-Safety data base S4740: Keep at temperature not exceeding 40 °C.
S48: Keep wet with ... (appropriate material to be specified by the manufacturer)
Merck S48.1: Keep wet with water.
Riedel-de Haen S48A: Keep wet with water.
S49: Keep only in the original container
S50: Do not mix with ... (to be specified by the manufacturer)
Merck S50.1: Do not mix with acids.
Merck S50.2: Do not mix with lyes.
Merck S50.3: Do not mix with strong acids or lyes, nonferrous heavy metals and their salts.
S51: Use only in well-ventilated areas.
S52: Not recommended for interior use on large surface areas.
S53: Avoid exposure - obtain special instructions before use.
S54 (obsolete): Before draining of to sewage disposal plant ask for permission of the competent authority.
(This S-phrase is no longer designated by the version of  the GefStoffV published on 26.10.93.)
S55 (obsolete): Before draining of into the sewage system or into waters treat according to state of art.
(This S-phrase is no longer designated by the version of  the GefStoffV published on 26.10.93.)
S56: Dispose of this material and its container at hazardous or special waste collection point.
S57: Use appropriate container to avoid environmental contamination.
S58 (obsolete): Dispose as hazardous waste.
(This S-phrase is no longer designated by the version of  the GefStoffV published on 26.10.93.)
S59: Refer to manufacturer/supplier for information on recovery/recycling
S60: This material and its container must be disposed of as hazardous waste.
S61: Avoid release to the environment. Refer to special instructions / Safety data sheets.
S62: If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
S63: In case of accident by inhalation: remove casualty to fresh air and keep at rest.
S64: If swallowed, rinse mouth with water (only if the person is conscious).

Combinations of S Phrases:

S1/2: Keep locked up and out of the reach of children.
S3/7: Keep container tightly closed in a cool place.
S3/7/9 (obsolete): Keep container tightly closed in a cool, well-ventilated place.
S3/9 (obsolete): Keep container in a cool, well-ventilated place.
S3/9/14: Keep in a cool, well-ventilated place away from ... (incompatible materials to be indicated by the manufacturer)
S3/9/14/49: Keep only in the original container in a cool, well-ventilated place away from ... (incompatible materials to be indicated by the manufacturer)
S3/9/49: Keep only in the original container in a cool well-ventilated place.
S3/14: Keep in a cool place away from ... (incompatible materials to be indicated by the manufacturer)
S7/8: Keep container tightly closed and dry.
S7/9: Keep container tightly closed and in a well-ventilated place.
S7/47: Keep container tightly closed and at a temperature not exceeding ... °C (to be specified by the manufacturer).
S20/21: When using do not eat, drink or smoke.
S24/25: Avoid contact with skin and eyes.
S27/28: Take off immediately all contaminated clothing. After contact with skin, wash immediately with plenty of ......(to be specified by the manufacturer)
S29/35: Do not empty into drains. This material and its container must be disposed of in a safe way.
S29/56: Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point.
S36/37: Wear suitable protective clothing and gloves.
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
S36/39: Wear suitable protective clothing and eye/face protection.
S37/39: Wear suitable gloves and eye/face protection.
S47/49: Keep only in the original container at a temperature not exceeding ... °C (to be specified by the manufacturer)

Burkhard Kirste, 1994-07-08, Thomas Lehmann, 1996-01-02; last modification: 2009-01-21



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